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Abstract We use in situ measurements from the first 19 encounters of Parker Solar Probe and the most recent five encounters of Solar Orbiter to study the evolution of the turbulent sonic Mach numberM_t(the ratio of the amplitude of velocity fluctuations to the sound speed) with radial distance and its relationship to density fluctuations. We focus on the near-Sun region with radial distances ranging from about 11 to 80R_⊙. Our results show that (1) the turbulent sonic Mach numberM_tgradually moves toward larger values as it approaches the Sun, until at least 11R_⊙, whereM_tis much larger than the previously observed value of 0.1 at and above 0.3 au; (2) transonic turbulence withM_t ∼ 1 is observed in situ for the first time and is found mostly near the Alfvén critical surface; (3) Alfvén Mach number of the bulk flowM_Ashows a strong correlation with the plasma beta, indicating that most of the observed sub-Alfvénic intervals correspond to a low-beta plasma; (4) the scaling relation between density fluctuations andM_tgradually changes from a linear scaling at larger radial distances to a quadratic scaling at smaller radial distances; and (5) transonic turbulence is more compressible than subsonic turbulence, with enhanced density fluctuations and slightly flatter spectra than subsonic turbulence. A systematic understanding of compressible turbulence near the Sun is necessary for future solar wind modeling efforts. 

Abstract Magnetic field fluctuations measured in the heliosheath by the Voyager spacecraft are often characterized as compressible, as indicated by a strong fluctuating component parallel to the mean magnetic field. However, the interpretation of the turbulence data faces the caveat that the standard Taylor’s hypothesis is invalid because the solar wind flow velocity in the heliosheath becomes subsonic and slower than the fast magnetosonic speed, given the contributions from hot pickup ions (PUIs) in the heliosheath. We attempt to overcome this caveat by introducing a 4D frequency-wavenumber spectral modeling of turbulence, which is essentially a decomposition of different wave modes following their respective dispersion relations. Isotropic Alfvén and fast mode turbulence are considered to represent the heliosheath fluctuations. We also include two dispersive fast wave modes derived from a three-fluid theory. We find that (1) magnetic fluctuations in the inner heliosheath are less compressible than previously thought, an isotropic turbulence spectral model with about 25% in compressible fluctuation power is consistent with the observed magnetic compressibility in the heliosheath; (2) the hot PUI component and the relatively cold solar wind ions induce two dispersive fast magnetosonic wave branches in the perpendicular propagation limit, PUI fast wave may account for the spectral bump near the proton gyrofrequency in the observable spectrum; (3) it is possible that the turbulence wavenumber spectrum is not Kolmogorov-like although the observed frequency spectrum has a −5/3 power-law index, depending on the partitioning of power among the various wave modes, and this partitioning may change with wavenumber. 

Hybrid superconductor–semiconductor materials systems are promising candidates for quantum computing applications. Their integration into superconducting electronics has enabled on-demand voltage tunability at millikelvin temperatures. Ge quantum wells have been among the semiconducting platforms interfaced with superconducting Al to realize voltage tunable Josephson junctions. Here, we explore Nb as a superconducting material in direct contact with Ge channels by focusing on the solid-state reactions at the Nb/Ge interfaces. We employ Nb evaporation at cryogenic temperatures (∼100 K) to establish a baseline structure with atomically and chemically abrupt Nb/Ge interfaces. By conducting systematic photoelectron spectroscopy and transport measurements on Nb/Ge samples across varying annealing temperatures, we elucidated the influence of Ge out-diffusion on the ultimate performance of superconducting electronics. This study underlines the need for low-temperature growth to minimize chemical intermixing and band bending at the Nb/Ge interfaces. 

Using methane as a reagent to synthesize high-value chemicals and high-energy density fuels through C−C coupling has attracted intense attention in recent decades, as it avoids completely breaking all C−H bonds in CH4. In the present study, we demonstrated that the coupling of HCHO with the CH3 species from CH4 activation to produce ethanol can be accomplished on the single Pd atom−In2O3 catalyst based on the results of density functional theory (DFT) calculations. The results show that the supported single Pd atom stabilizes the CH3 species following the activation of one C−H bond of CH4, while HCHO adsorbs on the neighboring In site. Facile C−C coupling of HCHO with the methyl species is achieved with an activation barrier of 0.56 eV. We further examined the C−C coupling on other single metal atoms, including Ni, Rh, Pt, and Ag, supported on In2O3 by following a similar pathway and found that a balance of the three key steps for ethanol formation, i.e., CH4 activation, C−C coupling, and ethoxy hydrogenation, was achieved on Pd/In2O3. Taking the production of acetaldehyde and ethylene on the Pd/In2O3 catalyst into consideration, the DFT-based microkinetic analysis indicates that ethanol is the dominant product on the Pd/In2O3 catalyst. The facile C−C coupling between HCHO and dissociated CH4 makes formaldehyde a potential C1 source in the conversion and utilization of methane through an energy- and atom-efficient process. 

Stress-strain responses and twinning characteristics are studied for a rolled AZ31B magnesium alloy under three different stress states: tension along the normal direction (NDT), compression along the rolled direction (RDC), and torsion about the normal direction (NDTOR) using companion specimens interrupted at incremental strain levels. Tension twinning is extensively induced in twinning-favorable NDT and RDC. All the six variants of tension twin are activated under NDT, whereas a maximum of four variants is activated under RDC. Under NDTOR, both tension twins and compression twins are activated at relatively large strains and twinning occurs in a small fraction of favored grains rather than in the majority of grains. Secondary and tertiary twins are observed in the favorably-orientated grains at high strain levels. Deformation under each stress state shows three stages of strain hardening rate: fast decrease (Stage I), sequential increase (Stage II), and progressive decrease (Stage III). The increase in the hardening rate, which is more significant under NDT and RDC as compared to NDTOR, is attributed to the hardening effect of twin boundaries and twinning texture-induced slip activities. The hardening effect of twin boundaries include the dynamic Hall-Petch hardening induced by the multiplication of twin boundaries (TBs) and twin-twin boundaries (TTBs) as well as the hardening effect associated with the energetically unfavorable TTB formation. When the applied plastic strain is larger than 0.05 under NDT and RDC, the tension twin volume fraction is higher than 50%. The twinning-induced texture leads to the activation of non-basal slips mainly in the twinned volume, i.e. prismatic slips under NDT and pyramidal slips under RDC. The low work hardening under NDTOR is due to the prevailing basal slips with reduced twinning activities under NDTOR. 

Enzyme encapsulation in metal-organic frameworks (MOFs)/covalent-organic frameworks (COFs) provides advancement in biocatalysis, yet the structural basis underlying the catalytic performance is challenging to probe. Here, we present an effective protocol to determine the orientation and dynamics of enzymes in MOFs/COFs using site-directed spin labeling and electron paramagnetic resonance spectroscopy. The protocol is demonstrated using lysozyme and can be generalized to other enzymes.